Alfred Irénée du Pont (1864-1935) was the eldest son of E.I. du Pont (1829-1877). He joined the family gunpowder firm in 1884. This item is portrait of Alfred I. du Pont, dated September 1881.

Alexis I. du Pont (1816-1857) was proprieter of his family business, E.I. du Pont de Nemours & Company, which began in the manufacture of gunpowder in 1802. He was the youngest child of Eleuthère Irénée du Pont (1771-1834), the founder of the DuPont Company. This collection contains thirteen photographic items, mostly portraits of Alexis I. du Pont and other du Pont family members.

Henry du Pont (1812-1889) was the second son of Eleuthère Irénée du Pont (1771-1834) and senior partner of E.I du Pont de Nemours & Company from 1850 to 1889. The collection consists of materials relating to the descendants of Henry and Louisa Gerhard du Pont. Primarily, the collection consists of portraits and other photographs of their daughters Evelina, Ellen, Louisa, Sara, Victorine, Sophie and other family members.

Irene (Renee) Carpenter (1911-1991) was a descendant of Pierre Samuel du Pont de Nemours (1739-1817) who founded the E.I. du Pont de Nemours & Company with his son Eleuthère Irénée du Pont (1771-1834) in 1802. She was the second child of R.R.M. Carpenter (1877-1949) and Margaretta Lammot du Pont (1884-1973) and a granddaughter of Lammot du Pont (1831-1884). The collection consists of photographs of Irene Carpenter Draper, as a child and as a young adult, and her extended family.

Lammot du Pont Copeland (1905-1983) was an American businessman, great-great-grandson of E.I. du Pont (1771-1834), and chief executive officer of E.I. du Pont de Nemours & Company. This collection primarily consists of portrait photographs of members of the du Pont, Belin, Copeland, Gratiot, La Motte, and related families. There are also two small booklets containing prints of various du Pont and Cunningham homes.

Oskar Eduard Heinrich Held (1904-1981) married into the du Pont family, a prominent and historically wealthy American family of French descent, known for founding the E.I. du Pont de Nemours & Company in 1802. The E.I. du Pont de Nemours & Company is a chemical research and manufacturing company more commonly referred to as the DuPont Company. The collection features images related to the Crofton, du Pont, and Shubrick families between the mid-to-late nineteenth century. Researchers interested in genealogical, Civil War-era photography, and late nineteenth-century military installations would find this collection useful.