Alfred Victor du Pont (1900-1970) was a partner in the Wilmington, Delaware, architectural firm of Massena and Du Pont, and he was the third child of Alfred I. du Pont (1864-1935) and his first wife Bessie Gardner du Pont (1864–1949). This small collection includes both business and personal papers. The largest portion is made up of Alfred V. du Pont's correspondence with his father, Alfred I. du Pont.

Alice Belin du Pont (1872-1944) was a member of several social clubs and became very involved with philanthropic work. She was the daughter of Henry Belin Jr. (1843-1918) and Margaretta Lammot Belin (1846-1927), and wife of Pierre S. du Pont (1870-1954). The letter is from du Pont to Haynes Battan (1898-1979), a Longwood employee.

Louise du Pont Crowninshield (1877-1958) was an early leader in the field of historic preservation and a collector of antiques and hooked rugs. The collection includes her papers as well as those of her husband Francis Boardman Crowninshield, her mother, and other family members.