The Brandywine Manufacturers Sunday School (BMSS) was organized in 1817 as a non-sectarian school for the children of the local factory workers, with instruction in reading, writing, arithmetic, and religion. Éleuthère Irénée du Pont (1771-1834), founder of the DuPont Company, was one of its chief subscribers, and the school building was located on his property. Primarily generated and maintained by the du Pont women, the BMSS records include the school's constitution, and financial records such as bills, receipts, and accounts. Most of the records pertain to students with information about premiums which were given as rewards for attendance and scholarly excellence.

The Brandywine Manufacturers Sunday School (BMSS) was organized in 1817 as a non-sectarian school for the children of the local factory workers, with instruction in reading, writing, arithmetic, and religion. This collection contains eleven Kodachrome prints of exterior views of the school building taken by Nancy Wootten (of Wilmington), between 1963 and 1966.

Founded in 1848 by Reverend Samuel Brincklé (1796-1863) and members of the du Pont family, Christ Church Christian Hundred located in Greenville, Delaware is one of the oldest Episcopal churches in the Diocese of Delaware. Their records chronicle the activities of Christ Church over a span of nearly one hundred fifty years and include administrative and vital records.

E.I. du Pont de Nemours & Company was established in 1802 by Pierre Samuel du Pont de Nemours (1739-1817) and his son Éleuthère Irénée du Pont (1771-1834). This collection of more than 1250 discrete photographs depicts the landscape and buildings at or near the company's explosives manufacturing plants along Brandywine Creek near Wilmington, Delaware. Approximately 900 images depict powder yard sites, including the DuPont Experimental Station, either during the mills' final decades of operation or prior to, during, and after excavation and restoration work on the site in the 1950s and 1960s. Most of the remaining images depict the worker communities which surrounded the powder yards.

Eleuthère Irénée du Pont (1771-1834), founder of E.I. du Pont de Nemours & Co., and Sophie Madeleine Dalmas du Pont (1775-1828) had four daughters. This group of materials within the Winterthur Manuscripts collection contains the papers of the three eldest: Victorine (du Pont) Bauduy (1792-1861), Evelina (du Pont) Bidermann (1796-1863), and Eleuthera (du Pont) Smith (1806-1876), as well as their respective husbands: Ferdinand Bauduy (1791-1814), James Antoine Bidermann (1790-1865), and Thomas MacKie Smith (1809-1852). Victorine du Pont Bauduy and Eleuthera du Pont Smith were teachers at the Brandywine Manufacturers' Sunday School (BMSS), a nonsectarian school offering classes in reading, writing, arithmetic, and Bible lessons. Evelina du Pont Bidermann spent much of her adult life traveling alongside her husband and then building the Winterthur mansion in Delaware. Their papers document details about their education, social life, family, attitudes, and activities through incoming and outgoing correspondence, as well as personal papers such as diaries and account books.

Francis “Frank” Pierre Gentieu (1876-1950) was a ballistic engineer at E.I. du Pont de Nemours & Company, a chemical company more commonly referred to as the DuPont company. Gentieu worked at DuPont's Carney's Point Plant in New Jersey from 1901 to 1941. This small collection contains an account by Gentieu entitled "The First Fifty Years at Carney's Point" (1891-1941); correspondence with du Pont family members; a list of his father Pierre Gentieu's photographs of the DuPont Company and Brandywine area; and a recollection written by Samuel Brown of a conversation with Sophie M. du Pont (1810-1888) related to the Brandywine Manufacturers Sunday School.