E.I. du Pont de Nemours & Company was established in 1802 by Pierre Samuel du Pont de Nemours (1739-1817) and his son Éleuthère Irénée du Pont (1771-1834). This collection of more than 1250 discrete photographs depicts the landscape and buildings at or near the company's explosives manufacturing plants along Brandywine Creek near Wilmington, Delaware. Approximately 900 images depict powder yard sites, including the DuPont Experimental Station, either during the mills' final decades of operation or prior to, during, and after excavation and restoration work on the site in the 1950s and 1960s. Most of the remaining images depict the worker communities which surrounded the powder yards.

E. Paul du Pont (1887-1950) established Du Pont Motors, Inc., a manufacturing company of luxury automobiles, in 1919 in Wilmington, Delaware. He worked for a short time at the family business, E.I. du Pont de Nemours & Company which manufactured gunpowder. He was one of ten children of Francis Gurney du Pont (1850-1904) and Eliza Wigfa Simons du Pont (1849-1919). This small collection contains photographs of DuPont powder yards; family photographs; home exteriors; and postcard views of Longwood Gardens.

E.I. du Pont de Nemours & Company is a chemical company more commonly referred to as the DuPont company. The company was established in 1802 by Pierre Samuel du Pont de Nemours (1739-1817) and his son Eleuthère Irénée du Pont (1771-1834) the company began with the production of gunpowder. This image is an exterior partially obscured view of a glaze mill near the Brandywine River used in the manufacture of DuPont Company black powder and explosives.

Francis Gurney du Pont (1850-1904) was the youngest son of Alexis I. du Pont (1816-1857) and Joanna Smith du Pont (1815-1876), and grandson of Éleuthère Irénée "E.I." du Pont (1771-1834), founder of E.I. du Pont de Nemours & Company, a chemical company more commonly referred to as the DuPont Company. The papers consist of du Pont's student lecture and laboratory notes; letters; technical notes and papers; records of gunpowder production; patent specifications and drawings; patent correspondence; and printed patents related to gunpowder.

Alfred Victor du Pont (1798-1856), son of Sophie Madeleine Dalmas (1775-1828) and Eleuthère Irénée du Pont (1771-1834), the founder of the E.I. du Pont de Nemours & Company. He joined the company in 1818, after an explosion that killed thirty-three people. The maps in this collection depict the Hagley yard based on an 1834 survey done by du Pont.

Pierre A. Gentieu (1842-1930) was a long-time employee of E.I. du Pont de Nemours & Company. Gentieu was born in France in 1842. He emigrated to the United States around 1859. He began working for DuPont in 1877. This collection is comprised of images taken by DuPont Company employee Pierre Gentieu from approximately 1880 to 1920. Gentieu's images document the DuPont Company Powder Yards along the banks of the Brandywine River in Wilmington Delaware. The collection documents the surrounding community along the Brandywine including worker's families, du Pont family homes, churches in the area, DuPont Company exposition displays, and other facets of social and work life in the area.

The pulp keg mill was built around 1904 to manufacture an experimental design of black and smokeless powder container made essentially from paper. This album contains photographic prints of the construction of the pulp keg mill in the Hagley Yard of E.I. du Pont de Nemours & Co. near Wilmington, Delaware around 1902 through 1905.