Alexis I. du Pont (1816-1857) was proprieter of his family business, E.I. du Pont de Nemours & Company, which began in the manufacture of gunpowder in 1802. He was the youngest child of Eleuthère Irénée du Pont (1771-1834), the founder of the DuPont Company. This collection contains thirteen photographic items, mostly portraits of Alexis I. du Pont and other du Pont family members.

Lammot du Pont Copeland (1905-1983) was an American businessman, great-great-grandson of E.I. du Pont (1771-1834), and chief executive officer of E.I. du Pont de Nemours & Company. This collection primarily consists of portrait photographs of members of the du Pont, Belin, Copeland, Gratiot, La Motte, and related families. There are also two small booklets containing prints of various du Pont and Cunningham homes.