Emma E. Holmes (1838-1910) was the daughter of Dr. Henry M. Holmes (1790-1854) and Eliza Ford Gibbes (1808-1875). The diary chronicles Holmes's life in Charleston, South Carolina, during the Civil War, detailing the Charleston fire of December 1861, visiting army camps, taking a position as governess and tutor, and plundering Union troops near the end of the war.

Manigault's papers consist of her own diaries and correspondence between her and Gabrielle Josephine du Pont (1770-1836), both which document the life of a female member of Charleston's merchant-planter elite during the Early National Period, and the web of connections linking Charleston, New York and Philadelphia society.

Samuel Francis du Pont (1803-1865) was a Rear Admiral in the United States Navy and fought in the Mexican-American War and the Civil War. He was the fourth child and second surviving son of Victor Marie du Pont (1767-1827) and his wife, Gabrielle Joséphine de la Fite de Pelleport (1770-1837). The two letters from du Pont to Charles G. Halpine (1829-1868) are written during the Civil War and relate to ironclads and the evacuation of Charleston, South Carolina.