Alfred Victor du Pont (1900-1970) was a partner in the Wilmington, Delaware, architectural firm of Massena and Du Pont, and he was the third child of Alfred I. du Pont (1864-1935) and his first wife Bessie Gardner du Pont (1864–1949). This small collection includes both business and personal papers. The largest portion is made up of Alfred V. du Pont's correspondence with his father, Alfred I. du Pont.

The Hiebler family papers include documents pertaining to four generations. The bulk of the collection consists of letters written by Alfred I. du Pont to his grandsons Bayard Hiebler and Benno Hiebler, dated 1927 to 1935.