The du Pont family is a prominent Delawarean family descended from Pierre Samuel du Pont de Nemours (1739-1817), who founded E.I. du Pont de Nemours & Company with his son, Eleuthère Irénée du Pont (1771-1834), in 1802. E.I. du Pont de Nemours & Company is a chemical research and manufacturing company more commonly referred to as the DuPont Company. This collection consists of placemats with images of exterior views of eight du Pont family homes.

Maurice du Pont Lee (1885-1974) was the General Advisor to the Chief Engineer of E.I. du Pont de Nemours & Company. The collection includes photographs of Maurice du Pont Lee's family members. The collection also includes a group of public relations photographs of Maurice du Pont Lee, dating from 1950 to 1969.

T. Coleman (Thomas Coleman) du Pont (1863-1930) was President of the DuPont Company from 1902 to 1915, and a U.S. Senator from Delaware from 1921 to 1928. He married Alice du Pont (1863-1937) in 1891. The "Old Mill" was constructed in 1909 to 1910 as a weekend home for T. Coleman du Pont in an area near Greenville, Delaware. These photographs document the Old Mill, retreat of T. Coleman du Pont, and the surrounding gardens planted by his wife, Alice.

Andrew Gray Wilson (1844-1905) was well-known among shipbuilders as a preeminent marine engineer and naval architect. This small collection consists primarily of individual and group portraits and snapshots of the Wilson family and the family of one of the daughters, Natalie Wilson du Pont. The collection is organized into three series; family photographs; home interiors and exteriors; and family cars and dogs photographs.