Francis Gurney du Pont (1850-1904) was the youngest son of Alexis I. du Pont (1816-1857) and Joanna Smith du Pont (1815-1876), and grandson of Éleuthère Irénée "E.I." du Pont (1771-1834), founder of E.I. du Pont de Nemours & Company, a chemical company more commonly referred to as the DuPont Company. The papers of du Pont describe both his business activities at E.I. du Pont de Nemours & Company, his family life, and his activities in the Episcopal Church.

Pierre A. Gentieu (1842-1930) was a long-time employee of E.I. du Pont de Nemours & Company. Gentieu was born in France in 1842. He emigrated to the United States around 1859. He began working for DuPont in 1877. This collection is comprised of images taken by DuPont Company employee Pierre Gentieu from approximately 1880 to 1920. Gentieu's images document the DuPont Company Powder Yards along the banks of the Brandywine River in Wilmington Delaware. The collection documents the surrounding community along the Brandywine including worker's families, du Pont family homes, churches in the area, DuPont Company exposition displays, and other facets of social and work life in the area.

Pierre Samuel "P.S." du Pont (1870-1954) was an industrialist, entrepreneur, and philanthropist. He was president of E.I. du Pont de Nemours & Company from 1915 to 1919 and chairman of the board of directors from 1919 to 1940. P.S. du Pont was the great-grandson of Eleuthère Irénée du Pont (1771-1834), founder of E.I. du Pont de Nemours & Company, and the great-great-grandson and namesake of the French economist Pierre Samuel du Pont de Nemours (1739-1817). During the early 1920s, P.S. du Pont became an active collector of Du Pont materials, and bought several important bodies of manuscripts from French dealers. This collection consists of manuscripts he collected that are primarily concerned with Du Pont de Nemours, the Physiocrats, the French Revolution, and the antecedents of the Du Ponts and allied families in France. The collection also contains the Wilmington & Kennett Turnpike Co. records dating from 1811 to 1921 that were acquired by P.S. du Pont from 1919 to 1920 when he purchased the company's stock, widened the road, and turned over its administration to the Delaware State Highway Department.

Pierre Samuel "P.S." du Pont (1870-1954) was president of E.I. du Pont de Nemours & Co. (more commonly known as the DuPont Company or simply DuPont) from 1915 to 1919 and chairman of the board from 1919 to 1940. P.S. du Pont was the great grandson of Eleuthere Irenee du Pont (1771-1834), founder of E.I. du Pont de Nemours & Company. He was also an avid collector of documents on the early history of the du Pont family and the DuPont Company. This collection contains elements which were selected from both company and family papers. The material was lodged in du Pont's Wilmington office for a number of years prior to his death in 1954.