Pierre Samuel du Pont de Nemours (1739-1817) was a French political economist, writer, publisher, and public administrator. Anne Louise Germaine de Staël-Holstein (1766-1817), known as Madame de Staël, was a writer, philosopher, and politically engaged woman who survived the French Revolution and was exiled multiple times by Napoleon Bonaparte (1769-1821). This collection contains two letters, one by du Pont de Nemours and one by de Staël. His letter was written the night the Bastille was stormed. Her undated letter concerns French relations with Sweden.

Pierre Samuel "P.S." du Pont (1870-1954) was an industrialist, entrepreneur, and philanthropist. He was president of E.I. du Pont de Nemours & Company from 1915 to 1919 and chairman of the board of directors from 1919 to 1940. P.S. du Pont was the great-grandson of Eleuthère Irénée du Pont (1771-1834), founder of E.I. du Pont de Nemours & Company, and the great-great-grandson and namesake of the French economist Pierre Samuel du Pont de Nemours (1739-1817). During the early 1920s, P.S. du Pont became an active collector of Du Pont materials, and bought several important bodies of manuscripts from French dealers. This collection consists of manuscripts he collected that are primarily concerned with Du Pont de Nemours, the Physiocrats, the French Revolution, and the antecedents of the Du Ponts and allied families in France. The collection also contains the Wilmington & Kennett Turnpike Co. records dating from 1811 to 1921 that were acquired by P.S. du Pont from 1919 to 1920 when he purchased the company's stock, widened the road, and turned over its administration to the Delaware State Highway Department.