Irénée du Pont (1876-1963) was a chemical engineer. He began work for E.I. du Pont de Nemours & Co. in 1903 in the Construction Division of the Black Powder Operating Department. After holding several positions within the company he went on to be the president of the DuPont Company. He served in this capacity from 1919 until 1926. The collection consists of photographs related to Irénée du Pont's family, personal interests, and involvement with organizations such as the Delaware Safety Council.

William Winder ‘Chick” Laird, Jr. (1910-1989) was a director of E. I. du Pont de Nemours and a financial advisor, starting his own brokerage firm in Wilmington, Delaware. This collection includes photographs of interiors and exteriors of du Pont family estates and homes in Delaware, as well as portraits and snapshots of du Pont and Laird family members. The collection also contains a large number of lantern slides, blueprints, maps, and film reels of home movies and family skits.