DuPont Company employees series dates from 1937 to 1987 and contains group portraits of Experimental Station executives, proofs of articles for DuPont Today magazine, one issue of DuPont Today, portraits of Crawford H. Greenewalt, Salim Ibrahim and Charles J. Pedersen and a chart titled "CIS-IFS-ABS update." There are also three certificates which were awarded to the DuPont Company from professional organizations.

The series has been divided into subseries pertaining to Charles Schwab, Eugene Grace, Individuals, Board of Directors, and Group photographs. In addition to portraits of these men, there are views of their estates (including Schwab's "Riverside" in Manhattan designed by architect Maurice Herbert (dates unknown) and "Immergrun," his Loretto, Pennsylvania, estate with gardens designed by Charles Wellford Leavitt (1871-1928) in 1915), travel photographs, and personal items. There is another file of ninety-five portraits of men who were related to the steel industry.

The Individuals and families series includes includes du Pont, his family and extended family, friends and associates. The images are mostly individual portraits of identified people, over half of this series contains photographs of various du Pont family members, with particular emphasis on P.S. du Pont. There are group portraits and snapshots of families, many identified, but not always. Most of the photographs are original and there are a few original engravings, however, there are also many photographic reproductions of engravings, paintings, or drawings of those who lived prior to the invention of photography in 1826. There are glass and film negatives taken by P.S. du Pont himself. Many of these are from his youth; for example, the 65 negatives taken at Phillips Academy where his brother was a student. There are albums of cartes de visite of which many of the subjects are identified and also an album once in the possession of Henry Algernon du Pont containing Civil War-era military officers (predominantly physicians) and military scenes. There is a two-volume set of du Pont de Nemours family portraits that was printed for the 100 anniversary of the family and an album of the 150th family reunion in 1950. The albums are listed in the beginning of the series, followed by individuals/families listed alphabetically by last name.