Pierre Samuel du Pont de Nemours (1739-1817) was a French political economist, writer, publisher, and public administrator. He was an advocate for a national educational system and promoted Franco-American trade relations. Françoise (Robin) Poivre (1748-1841) was the second wife of Pierre Samuel. Françoise Julienne Ile de France (Poivre) Bureaux de Pusy (1770-1845) was a daughter from Poivre's first marriage. This collection includes a small selection of correspondence, including details on the family's immigration to the United States from France and Bureaux de Pusy's financial problems.