The correspondence is primarily personal but contains frequent references to business matters. The bulk of the letters were written by du Pont to his wife, father, and brother. Matters discussed include the Paris printing operations, the firm of du Pont de Nemours, Père et Fils & Cie., the financial affairs of Victor du Pont, E.I. du Pont's horticultural and botanical interests, the patronage of Thomas Jefferson in furthering the successs of the powder company, the establishment of ancillary leather, cotton and woolen manufacturing enterprises on the Brandywine, the tariff issue, the importation of Merino sheep, community affairs, and the education of du Pont's children.

Pierre Samuel du Pont de Nemours (1739-1817) was a French political economist, writer, publisher, and public administrator. Anne Louise Germaine de Staël-Holstein (1766-1817), known as Madame de Staël, was a writer, philosopher, and politically engaged woman who survived the French Revolution and was exiled multiple times by Napoleon Bonaparte (1769-1821). This collection contains six photocopied letters of du Pont de Nemours to Thomas Jefferson (1743-1826), and de Staël letters to unknown correspondents. The letters include references to the political situation in France, services of du Pont de Nemours printing establishment, and national affairs.

Pierre Samuel du Pont de Nemours (1739-1817) was a French political economist, writer, publisher, and public administrator. In 1800, accompanied by his sons, Victor Marie du Pont (1767-1827) and Eleuthère Irénée "E.I." du Pont (1771-1834), he arrived in America. In 1802, E.I. du Pont established E.I. du Pont de Nemours & Company, which began manufacturing gunpowder. This item is a letter written to President Thomas Jefferson about du Pont de Nemours' son, E.I. du Pont, as a gunpowder manufacturer and requesting Jefferson's opinon on the matter of refining saltpetre.

Pierre Samuel du Pont de Nemours (1739-1817) was a French political economist, writer, publisher, and public administrator. He was an advocate for a national educational system and promoted Franco-American trade relations. The collection consists of Pierre Samuel du Pont de Nemours correspondence and writings in addition to correspondence of his second wife, Françoise (Robin) Poivre.